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在发现碳纳米管后不久,对于这些有趣结构的力学性质--包括高强度、高硬度、低密度和结构的完美性的理论预测,使人们认识到它们可能具有理想的科技应用价值.对这些预测的实验验证或个别验伪以及大量基于不同模型的计算机模拟方法,使得逾10年来对碳纳米管力学的理解日趋深入但远未达到尽头.本文回顾了理论预测,并对这种微小结构的观察和操作中经常用到的富有挑战性的实验技术进行了讨论.略述了采用的计算方法包括从头算法量子力学模拟、经典分子动力学和连续介质模型.多尺度和多物理模型的发展和模拟工具自然而然作为连接基础科学问题和工程应用的结果而出现,而这个主题仍然正在抓紧研究中.这里介绍了研究此主题的一些方法.注意力主要集中于研究力学性质的揭示方面,如杨氏模量、弯曲刚度、屈曲准则、拉伸和压缩强度.最后,讨论了利用这些性质的几个令人兴奋的应用例子,包括纳米绳束、填充的纳米管、纳米机电系统、纳米传感器和纳米管增强复合材料,引用了349篇参考文献. 图41参349 相似文献
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Results from a series of multiaxial loading experiments on the Ti–6Al–4V titanium alloy are presented. Different loading conditions are applied in order to get the comprehensive response of the alloy. The strain rates are varied from the quasi-static to dynamic regimes and the corresponding material responses are obtained. The specimen is deformed to large strains in order to study the material behavior under finite deformation at various strain rates. Torsional Kolsky bar is used to achieve shear strain rates up to 1000 s−1. Experiments are performed under non-proportional loading conditions as well as dynamic torsion followed by dynamic compression at various temperatures. The non-proportional loading experiments comprise of an initial uniaxial loading to a certain level of strain followed by biaxial loading, using a channel-type die at various rates of loadings. All the non-proportional experiments are carried out at room temperature. Experiments are also performed to investigate the anisotropic behavior of the alloy. An orthotropic yield criterion [proposed by Cazacu, O., Plunkett, B., Barlat, F., 2005. Orthotropic yield criterion for hexagonal closed packed metals. International Journal of Plasticity 22, 1171–1194.] for anisotropic hexagonal closed packed materials with strength differential is used to generate the yield surface. Based on the definition of the effective stress of this yield criterion, the observed material response for the different loading conditions under large deformation is modeled using the Khan–Huang–Liang (KHL) equation assuming isotropic hardening. The model constants used in the present study, were pre-determined from the extensive uniaxial experiments presented in the earlier paper [Khan, A.S., Suh, Y.S., Kazmi R., 2004. Quasi-static and dynamic loading responses and constitutive modeling of titanium alloys. International Journal of Plasticity 20, 2233–2248]. The model predictions are found to be extremely close to the observed material response. 相似文献
994.
实验教学中创新能力的培养 总被引:2,自引:1,他引:1
在物理实验教学中,难点是学生创新能力的培养,本结合物理实验的特点。简要论述了培养创新能力需要解决的主要问题,达到培养学生分析问题和解决问题的目的。 相似文献
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Evan D. Hudspeth Danielle Cleveland Kathleen L. Batchler Phuong A. Nguyen Tracey L. Feaser Lauren E. Quattrochi 《光谱学快报》2013,46(1):99-115
We have evaluated a small portable Raman instrument on loan from B&W Tek, Inc., and have determined that it can successfully be used in the classroom both as a visual aid for teaching the fundamentals of Raman spectroscopy and for a variety of undergraduate experiments as a normal component of an instrumental analysis class. Having portable Raman instrumentation would allow the instructor to demonstrate the principles of Raman spectroscopy, as well as the concepts of calibration curves, blank subtraction, detection limits, and regression analysis. Both qualitative and quantitative types of experiments were done for solid Tylenol tablets, aqueous solutions of isopropyl alcohol, dimethyl sulfoxide, methanol, and ethanol, and gaseous CO2 and N2O4. Additionally, surface‐enhanced resonance Raman spectra of Rhodamine 6G were obtained using a chloride ion–activated silver colloid. Spectra from the B&W Tek, Inc., instrument were comparable to literature Raman spectra. 相似文献
999.
Danielle Cleveland Matthew Carlson Evan D. Hudspeth Lauren E. Quattrochi Kathleen L. Batchler Shrimati A. Balram 《光谱学快报》2013,46(6):903-924
Raman spectroscopy has steadily gained popularity as a powerful tool in both the analytical lab and the undergraduate classroom. The technique is attractive because it allows for rapid, nondestructive qualitative or quantitative analyses of many analytes with little or no sample preparation requirements. The introduction of less expensive, smaller, and more powerful diode laser excitation sources and the recent availability of rugged, red‐sensitive, charge‐coupled device–based miniature modular spectrometers has prompted the integration of Raman spectroscopy into the undergraduate curriculum. We have evaluated the analytical utility of a small, portable Raman instrument for the qualitative and quantitative analyses of two “real” samples. The experiments in this paper were designed to be used as a laboratory component for undergraduate education and include the quantification of ethanol in consumer alcoholic beverages and the qualitative identification of marine diesel fuels that had been spilled on surface waters. In the case of the liquor samples, the ethanol concentration in colorless, odorless alcoholic beverages could be determined very rapidly, but colored and heavily scented liquors proved more difficult and required pretreatment with activated carbon to remove fluorescence that masked the Raman signal. Similarly, a high‐intensity fluorescence background was observed to mask characteristic Raman bands of the diesel fuels. Some reduction in the intensity of the fluorescence was observed after carbon pretreatment of the fuels. The set of undergraduate experiments described in this paper treat the concepts of quantitative and qualitative analysis using portable instrumentation, instrumental calibration by the standard addition and external curve methods, and method development for the analysis of real consumer and environmental samples. 相似文献
1000.
Naoki Kanata Takeshi Yoshikawa Yoshiharu Ohno Tomonori Kanda Koji Uchida Kenta Izaki Takumi Fukumoto Yonson Ku Tomoo Itoh Kazuhiro Kitajima Satoru Takahashi Kazuro Sugimura 《Magnetic resonance imaging》2013
The purpose of this study was to assess the efficacy of arterial-dominant phase images of gadolinium–ethoxybenzyl–diethylenetriamine pentaacetic acid (EOB)-enhanced magnetic resonance imaging (MRI) for evaluation of arterial blood supply in hepatocellular carcinoma (HCC) in comparison with that of multiphasic dynamic computed tomography (CT). This study comprised 30 patients (22 men and 8 women, mean age: 68.0 years) with 40 pathologically proven HCCs (well differentiated: 3, moderately differentiated: 30, poorly differentiated: 7, mean diameter: 45.1 mm), all of whom underwent EOB-enhanced MRI and dynamic CT preoperative assessment. Regions of interest were placed over HCCs and the adjacent normal liver, and signal intensities or CT values were measured by two experienced abdominal radiologists on the arterial-dominant phase images of EOB-enhanced MRI and dynamic CT images. HCC-to-liver contrasts [Michelson's contrast: CM=(SHCC− SLiver)/(SHCC+ SLiver)] were calculated and compared among the modalities. HCC-to-liver contrasts were also visually scored on a 5-point scale and compared. The mean CM and visual score for dynamic CT were significantly higher than those for EOB-enhanced MRI. Good agreements were obtained among the two observers. Dynamic CT is a more suitable modality than EOB-enhanced MRI for evaluation of arterial blood supply in HCC. This should be taken into account for diagnosis and management of HCC. 相似文献